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PTHH: \(CaCl_2+Na_2CO_3\rightarrow CaCO_3\downarrow+2NaCl\)
a+b) Ta có: \(n_{CaCl_2}=0,1\cdot2=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{CaCO_3}=0,2\left(mol\right)\\n_{NaCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,2\cdot100=20\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}\approx1,33\left(M\right)\end{matrix}\right.\)
c) PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
Theo PTHH: \(n_{HCl}=2n_{CaCO_3}=0,4\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\)
a.PTHH:CaCl2+Na2CO3--->CaCO3+2NaCl
Ta có:nCaCl2=0,2
=>nCaCO3=nCaCl2=0,2(mol)=>mCaCO3(kết tủa)=100.0,2=2(g)
b.Vdd=100+200=300(ml)=0,3(l)
CM Nacl=(2.0,2)/0,3=4/3(M)(Đề cho 2 chất td vừa đủ nên dd sau pứ chỉ có NaCl)
c.CaCO3+2HCl--->CaCl2+CO2+H2O
nHCl(cần dùng)=2.0.2=0,4(mol)=>mHCl=36,5.0,4=14,6(g)
=>mddHCl=14,6/10%=146(g)
\(n_{AgNO_3}=0,2.3=0,6\left(mol\right)\)
\(n_{AgNO_3\left(pư\right)}=\dfrac{0,6.20}{100}=0,12\left(mol\right)\)
PTHH: 2AgNO3 + Fe --> Fe(NO3)2 + 2Ag
_______a------>0,5a---->0,5a
Fe(NO3)2 + AgNO3 --> Fe(NO3)3 + Ag
_0,5a------->0,5a------->0,5a
=> a + 0,5a = 0,12
=> a = 0,08(mol)
=> mFe = 0,5.0,08.56 = 2,24(g)
b) \(\left\{{}\begin{matrix}C_{M\left(AgNO_3\right)}=\dfrac{0,6-0,12}{0,2}=2,4M\\C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,5.0,08}{0,2}=0,2M\end{matrix}\right.\)
\(300(ml)=0,3(l)\\ n_{HCl}=1.0,3=0,3(mol);n_{Fe}=\dfrac{5,6}{56}=0,1(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ \text{LTL: }\dfrac{n_{Fe}}{1}<\dfrac{n_{HCl}}{2}\Rightarrow HCl\text{ dư}\\ \Rightarrow n_{HCl(dư)}=0,3-0,1.2=0,1(mol)\\ \Rightarrow m_{HCl(dư)}=0,1.36,5=3,65(g)\\ b,n_{FeCl_2}=n_{Fe}=0,1(mol)\\ \Rightarrow \begin{cases} C_{M_{FeCl_2}}=\dfrac{0,1}{0,3}=0,33M\\ C_{M_{HCl(dư)}}=\dfrac{0,1}{0,3}=0,33M \end{cases}\)
a, Ta có: \(n_{KOH}=0,15.2=0,3\left(mol\right)\)
PT: \(KOH+HCl\rightarrow KCl+H_2O\)
Theo PT: \(n_{HCl\left(pư\right)}=n_{KOH}=0,3\left(mol\right)\)
Mà: HCl dư 15%
\(\Rightarrow n_{HCl}=0,3+0,3.15\%=0,345\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,345}{1,5}=0,23\left(l\right)\)
b, Theo PT: \(n_{KCl}=n_{KOH}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{KCl}}=\dfrac{0,3}{0,15+0,23}\approx0,789\left(M\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0,3.15\%}{0,15+0,23}\approx0,118\left(M\right)\)
nHCl=0,15 . 2=0,3(mol)
PTHH: CuO + 2 HCl -> CuCl2 + H2O
x___________2x____x(mol)
ZnO +2 HCl -> ZnCl2 + H2O
y______2y_____y(mol)
Ta có hpt: \(\left\{{}\begin{matrix}80x+81y=12,1\\2x+2y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)
Vddsau=VddHCl=0,15(l)
=> CMddCuO= 0,05/0,15=1/3(M)
CMddZnO=0,1/0,15=2/3(M)
a)
$Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O$
b)
n HCl = 0,4.1,5 = 0,6(mol)
n Al2O3 = 1/6 n HCl = 0,1(mol) => m = 0,1.102 = 10,2(gam)
n AlCl3 = 1/3 n HCl = 0,2(mol) => CM AlCl3 = 0,2/0,4 = 0,5M
\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Pt : \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,1 0,6 0,2
a) \(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{7,3}=300\left(g\right)\)
b) \(n_{FeCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)
⇒ \(m_{FeCl3}=0,2.162,5=32,5\left(g\right)\)
\(m_{ddspu}=16+300=316\left(g\right)\)
\(C_{FeCl3}=\dfrac{32,5.100}{316}=10,28\)0/0
\(a.n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ n_{HCl}=0,2.1,5=0,3\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,3}{2}< \dfrac{0,2}{1}\\ \Rightarrow Mgdư\\ n_{H_2}=n_{MgCl_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b.V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddMgCl_2}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)
$n_{CuO} = \dfrac{8}{80} = 0,1(mol) ; n_{HCl} = 0,15.2 = 0,3(mol)$
$CuO + 2HCl \to CuCl_2 + H_2O$
Ta thấy :
$n_{CuO} : 1 < n_{HCl} : 2$ nên HCl dư
$n_{CuCl_2} = n_{CuO} = 0,1(mol)$
$n_{HCl\ pư} = 2n_{CuO} = 0,2(mol) \Rightarrow n_{HCl\ dư} = 0,3 - 0,2 = 0,1(mol)$
$C_{M_{CuCl_2}} = \dfrac{0,1}{0,15} = 0,67M$
$C_{M_{HCl}} = \dfrac{0,1}{0,15} = 0,67M$